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What does this error message mean?

Error parsing sample groups.txt. Expected opening curly brace.

What does this mean and how can I fix it?
I only watch high quality video game rips.
How does your Addmusic_sample_groups.txt file looks like?
It looks like this:

#default
{
"default/00 SMW @0.brr"!
"default/01 SMW @1.brr"!
"default/02 SMW @2.brr"!
"default/03 SMW @3.brr"!
"default/04 SMW @4.brr"!
"default/05 SMW @8.brr"!
"default/06 SMW @22.brr"!
"default/07 SMW @5.brr"!
"default/08 SMW @6.brr"!
"default/09 SMW @7.brr"!
"default/0A SMW @9.brr"!
"default/0B SMW @10.brr"!
"default/0C SMW @13.brr"!
"default/0D SMW @14.brr"
"default/0E SMW @29.brr"!
"default/0F SMW @21.brr"
"default/10 SMW @12.brr"!
"default/11 SMW @17.brr"
"default/12 SMW @15.brr"!
"default/13 SMW Thunder.brr"!
}

#optimized
{
"optimized/00 SMW @0.brr"!
"optimized/01 SMW @1.brr"!
"optimized/02 SMW @2.brr"!
"optimized/03 SMW @3.brr"!
"optimized/04 SMW @4.brr"!
"optimized/05 SMW @8.brr"!
"optimized/06 SMW @22.brr"!
"optimized/07 SMW @5.brr"!
"optimized/08 SMW @6.brr"!
"optimized/09 SMW @7.brr"!
"optimized/0A SMW @9.brr"!
"optimized/0B SMW @10.brr"!
"optimized/0C SMW @13.brr"!
"optimized/0D SMW @14.brr"
"optimized/0E SMW @29.brr"!
"optimized/0F SMW @21.brr"
"optimized/10 SMW @12.brr"!
"optimized/11 SMW @17.brr"
"optimized/12 SMW @15.brr"!
"optimized/13 SMW Thunder.brr"!
}

#AMM
{
"Bass Drum.brr"!
"Bass.brr"
"Cymbol.brr"
"Electric Guitar.brr"
"Noise.brr"
"Snare Drum.brr"
"Square.brr"
"EMPTY.brr"
"EMPTY.brr"
"EMPTY.brr"
"EMPTY.brr"
"EMPTY.brr"
}

#50 bowser
{
"optimized/00 SMW @0.brr"!
"optimized/01 SMW @1.brr"!
"optimized/02 SMW @2.brr"!
"optimized/03 SMW @3.brr"!
"optimized/04 SMW @4.brr"!
"optimized/05 SMW @8.brr"!
"optimized/06 SMW @22.brr"!
"optimized/07 SMW @5.brr"!
"optimized/08 SMW @6.brr"!
"EMPTY.brr"
"optimized/0A SMW @9.brr"!
"optimized/0B SMW @10.brr"!
"optimized/0C SMW @13.brr"!
"EMPTY.brr"
"optimized/0E SMW @29.brr"!
"optimized/0F SMW @21.brr"
"optimized/10 SMW @12.brr"!
"EMPTY.brr"
"optimized/12 SMW @15.brr"!
"optimized/13 SMW Thunder.brr"!
}

I only watch high quality video game rips.
Originally posted by BoneyBrown
#50 bowser

I'm gonna guess it doesn't want spaces there. Rename to #50bowser.

If it still throws errors, then it probably doesn't want to start with a digit either, so try #bowser50. But I don't think that step is needed.

<blm> zsnes users are the flatearthers of emulation
I found it out, but thanks!
I only watch high quality video game rips.